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Swayam Central

Mechanisms in Organic Chemistry

By Prof. Nandita Madhavan   |   IIT Bombay
The course can be broadly classified as a Physical Organic Chemistry course. Understanding organic reaction mechanisms are extremely useful in predicting the products and improving the reaction efficiency. A student needs to know basic concepts in order to be able to write reasonable reaction mechanisms. A mechanism cannot be considered valid unless there is experimental evidence to support it. The student needs to know basic experiments that can be used to validate reaction mechanisms. Learning outcomes for the course: At the end of the course, the student should be able to • Propose/write a mechanism for a given organic reaction. • Design experiments to determine reaction intermediates/mechanisms. 

INTENDED AUDIENCE: Students studying Chemistry
PREREQUISITES:          Basic Organic Chemistry

SUMMARY

Course Status : Upcoming
Course Type : Core
Duration : 8 weeks
Start Date : 29 Jul 2019
End Date : 20 Sep 2019
Exam Date : 29 Sep 2019
Category :
  • Maths and Sciences
  • Level : Postgraduate
    This is an AICTE approved FDP course

    COURSE LAYOUT

    Week 1 : Basic concepts, Basics of Arrow pushing
    Week 2 : Polar reactions and Radical reactions
    Week 3 : Reaction coordinate diagrams, Kinetics of organic reactions, Kinetic versus thermodynamic control, Thermodynamics
    Week 4 : Thermodynamics (contd), Kinetics, Hammond’s postulate
    Week 5 : Kinetic versus Thermodynamic control, Steric effects, Curtin-Hammett Equation, Solvent effects, pH effects, 
    Week 6 : Determining nature of intermediate – LFER, Applications of LFER 
    Week 7 : Kinetic Isotope Effects, Equilibrium Kinetic Isotope Effects
    Week 8 : Mass balance, designing substrate, Checking for common intermediate, Isotope Labelling and trapping Cross-over experiments
    Summary



    BOOKS AND REFERENCES

    1. F. A. Carey and R. I. Sundberg, Advanced Organic Chemistry, Part A, 3rd edition, Plenum Press, 1990.
    2. E. V. Ansylyn, D. A. Dougherty Modern Physical Organic Chemistry. 
    3. Peter Sykes, A guidebook to mechanisms in Organic Chemistry. 

    INSTRUCTOR BIO



    Prof. Nandita Madhavan
    is an Associate Professor in the Department of Chemistry at Indian Institute of Technology Bombay(IITB).
    Post-doc,Univ. of Illinois at Urbana-Champaign, USA
    Assistant Professor, IIT Madras (2009),
    Associate Professor, IIT Madras (2015),
    Associate Professor, IIT Bombay (2016),
    Ph. D., Univ. of Illinois at Urbana-Champaign, USA,
    M. Sc., IIT Bombay,
    B. Sc., S. I. E. S. College, Mumbai

    COURSE CERTIFICATE

    • The course is free to enroll and learn from. But if you want a certificate, you have to register and write the proctored exam conducted by us in person at any of the designated exam centres.
    • The exam is optional for a fee of Rs 1000/- (Rupees one thousand only).
    • Date and Time of Exams: 29th September 2019 Morning session 9am to 12 noon; Afternoon Session 2pm to 5pm.
    • Registration url: Announcements will be made when the registration form is open for registrations.
    • The online registration form has to be filled and the certification exam fee needs to be paid. More details will be made available when the exam registration form is published. If there are any changes, it will be mentioned then.
    • Please check the form for more details on the cities where the exams will be held, the conditions you agree to when you fill the form etc.

    CRITERIA TO GET A CERTIFICATE
    • Average assignment score = 25% of average of best 6 assignments out of the total 8 assignments given in the course.
    • Exam score = 75% of the proctored certification exam score out of 100
    • Final score = Average assignment score + Exam score

    YOU WILL BE ELIGIBLE FOR A CERTIFICATE ONLY IF AVERAGE ASSIGNMENT SCORE >=10/25 AND EXAM SCORE >= 30/75
    • If one of the 2 criteria is not met, you will not get the certificate even if the Final score >= 40/100.
    • Certificate will have your name, photograph and the score in the final exam with the breakup.It will have the logos of NPTEL and IIT Bombay. It will be e-verifiable at nptel.ac.in/noc.
    • Only the e-certificate will be made available. Hard copies are being discontinued from July 2019 semester and will not be dispatched

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